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The diastereoselectivity of this reaction was studied. 0000073045 00000 n
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Ammonia Free Partial Reduction of Aromatic Compounds Using Lithium Di-tert-butylbiphenyl 0000002962 00000 n
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stable through conjugation, can be rationalized with a simple mnemonic. 0000110600 00000 n
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2018, 20, 3439-3442. 0000061733 00000 n
Subsequent functionalization to incorporate the lipophilic properties of the steroidal core afforded N-substituted perhydro-quinolinols as mimics of the AB-ring system of steroids. 0000058781 00000 n
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;pWҼ��":��p-�e The reaction involves the reaction of dissolving metals in ammonia with aromatic compounds to produce 1,4-cyclohexadienes. 0000073668 00000 n
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The question of why the 1,3-diene is not formed, even though it would be more stable through conjugation, can be rationalized with a simple mnemonic. 86�;�*!��p (LiDBB) ��C�h��sY;���==-� |��&�zI�m���ͺH���C҃Ok$@��@����n�%�C��Hꎏ��z >Z��$g8~�������8��ɍ}���9EK���7%g�a��c�g&����
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Myers Reduction Chem 115 R OR' O R H O O OMOM H N CH3 OMOM MOMO H3C O O O � :�q�0��!mQ���vĔ@˃_Ipt y�#�97d�/v�� �%�8��5�K�+�X�.g=*2��e 2002, 67, 5015-5018. 0000001432 00000 n
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the most highly substituted double bonds: The effect of electron-withdrawing substituents on the Birch Reduction 0000042953 00000 n
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Reduction of Carboxylic Acids Carboxylic acids, acid halides, esters, and amides are easily reduced by strong reducing agents, such as lithium aluminum hydride (LiAlH 4 ). the least change in electron distribution will be preferred. 0000016379 00000 n
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