; Shvyrev, V.V., Turner, J.J.; Simpson, M.B. Chem. A general reaction search Hiraoka, K.; Saluja, P.P.S. Chem., 1991, 417, 439. Torino, Classe Sci. J. [all data], Goebel, Haynes, et al., 1995 In addition to the Thermodynamics Research Center ; Feigerle, C.S. J. Chem. ; Gankin, V.Yu. Engelking, P.C. The heat of formation (in kJ) of carbon monoxide per mole is : Q. K from, Entropy of gas at standard conditions (1 bar), Temperature dependence parameter for Henry's Law constant, Enthalpy of formation of gas at standard conditions, Free energy of reaction at standard conditions, Enthalpy of reaction at standard conditions, Entropy of reaction at standard conditions. Acta, 1979, 33, 217. Soc., 1988, 110, 7, 2097, https://doi.org/10.1021/ja00215a014 Chem., 1982, 86, 2905. ; Ono, Y.; Ng, C.Y., J. Chem. Biol., 1915, 13, 312. Copyright for NIST Standard Reference Data is governed by Meot-Ner (Mautner), M.; Field, F.H., . Carbon Monoxide - Thermophysical Properties, STP - Standard Temperature and Pressure & NTP - Normal Temperature and Pressure, Boiling Point - saturation pressure 14.7 psia and 760 mm Hg - (, Latent Heat of Evaporation at boiling point (. . Rodgers, M.T. Am. ; Kickel, B.L., E/(2*t2) + G . Ion Phys., 1983, 47, 203, https://doi.org/10.1016/0020-7381(83)87171-X form is Follow the links below to get values for the listed properties of carbon monooxide at varying pressure and temperature: See also more about atmospheric pressure, and STP - Standard Temperature and Pressure & NTP - Normal Temperature and Pressure, as well as Thermophysical properties of: Acetone, Acetylene, Air, Ammonia, Argon, Benzene, Butane, Carbon dioxide, Ethane, Ethanol, Ethylene, Helium, Hydrogen, Hydrogen sulfide, Methane, Methanol, Nitrogen, Oxygen, Pentane, Propane, Toluene, Water and Heavy water, D2O. Mullins, J.C.; Kirk, B.S. All rights reserved. McQuaid, M.J.; Morris, K.; Gole, J.L., 28.012. [all data], Lewis, Golden, et al., 1984 J. Organometal. When calculating mass and volume flow of a substance in heated or cooled systems with high accuracy - the specific heat (= heat capacity) should be corrected according values in the table below. Mass Spectrom., 1998, 175, 1-2, 93, https://doi.org/10.1016/S0168-1176(98)00109-8 J. Chem. Daamen, H.; Ernsting, J.M. ; Bagratashvili, V.N. [all data], Bor and Dietler, 1980 [all data], Pajaro, Calderazzo, et al., 1960 However, NIST makes no warranties to that effect, and NIST Ligand effects in organometallic thermochemistry: The sequential bond energies of Ni(CO)x+ and Ni(N2)x+ (x = 1-4) and Ni(NO)x+ (x = 1-3) [Data derived from reported bond energies taking value of 8.273±0.046 eV for IE[Ni(CO)4]], Air - at Constant Pressure and Varying Temperature, Air - at Constant Temperature and Varying Pressure. ; Zaharani-Moettar, M.T., Khan, F.A. Details of Potential Energy Surfaces Involving C-C Bond Activation: Reactions of Fe+, Co+ and Ni+ with Acetone, Chem. AC - William E. Acree, Jr., James S. Chickos. Nolan, S.P. [all data], Hiraoka and Mori, 1989 Am. Phys. ; Skinner, H.A. Photoelectron Spectroscopy of Iron Carbonyl Cluster Anions (Fen(CO)m(-), n=1-4), [all data], Nolan, López de la Vega, et al., 1986 J. Boxhoorn, G.; Ernsting, J.M. J. Int. Chem. Am. ; Rosenfeld, R.N., ; Steele, D.L. Soc., 1984, 106, 7051. Stevens, A.E. Atti Accad. Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) ; Krinkin, D.P. J. Chem. The heat of formation (in kJ) of carbon monoxide per mole is: 676.5 –676.5 –110.5 110.5 Solution Combustion of Carbon: C + O 2 → CO 2; ΔH 1 = – 393.5 kJ / mole Combustion of Carbon Monoxide: CO + ½O 2 → CO 2; ΔH 2 2 J/(mol K) Gas properties Std enthalpy change of formation, Δ f H o gas −110.53 kJ/mol Std enthalpy change of combustion, Δ c Standard Reference Data Act. [all data], Tel'noi and Rabinovich, 1977 Organometallics, 1989, 8, 2471. been selected on the basis of sound scientific judgment. ; Pilcher, G.; Barnes, D.S. J. J. Chem. [all data], Pilcher, Ware, et al., 1975 J. ; solvent: n-Decane+cyclohexane mixture; The reaction enthalpy and entropy were identified with the enthalpy and entropy of activation for the reactions of Cr(CO)6(solution) with a phosphine and an amine. Phys., 1988, 89, 4092. Google use cookies for serving our ads and handling visitor statistics. kJ/mol Standard molar entropy, S o liquid? Gas Phase Stabilities of the Cluster Ions H+(CO)2(CO)n, H+(N2)2(N2)n and H+(O2)2(O2)n with n = 1 - 14, Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X View plot 0. Am. Am. [all data], Norwood, Guo, et al., 1988 The heat capacity and entropy of carbon monoxide. such sites. The results were quoted from, solvent: Decalin; Calculated from equilibrium and kinetic data, solvent: Decalin; Calculated from data for the reactions Os3(CO)10(H)2(solution) + CO(solution) = Os3(CO)11(H)2(solution) (hrxn [kJ/mol]=-39.7±1.3, srxn [J/(mol K)]=-80.3±3.8) and Os3(CO)11(H)2(solution) + CO(solution) = Os3(CO)12(solution) + H2(g) (hrxn [kJ/mol]=-37.7±9.6, srxn [J/(mol K)]=-32.6±27.6). J. Organomet. [all data], Graham and Angelici, 1967 ; Smith, R.T.; Zheng, Y., Vapor pressures of solid and liquid. ; Skinner, H.A. Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. Nat., 1963, 97, 1197. Barnes, D.S. The standard enthalpy of formation of NH 3 is– 46.0 kJmol –1. Lett., 1994, 221, 5-6, 436, https://doi.org/10.1016/0009-2614(94)00301-7 Material Properties - Material properties for gases, fluids and solids - densities, specific heats, viscosities and more ; Related Documents . Clayton, J.O. Am. Some of our calculators and applications let you save application data to your local computer. The reaction enthalpy at 298 K relies on an activation energy of 163.2 kJ/mol and assumes a negligible activation barrier for product recombination. RCD - Robert C. Dunbar Chem., 1935, 221, 321. Jennings, K.R. Nakajima, A.; Taguwa, T.; Kaya, K., [all data], Ungváry, 1972 ; Wagman, D.D. Chem. Ind. ; Kebarle, P., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. Russ. If you are not sure what that term means, please make sure to find out. It is highly recommended that you seek the material safety data sheet (MSDS) for this chemical from a reliable source such as SIRI, and follow its directions. J. Laser photoelectron spectrometry of the negative ions of iron and iron carbonyls. . . Thanks! Microcalorimetric studies. Organometallic bond dissociation energies. Electron affinity determination for the series Fe(CO)n,n=0,1,2,3,4, gas phase; determined from MKER and theory; solvent: Liquid krypton; The reaction enthalpy relies on the experimental value for the activation enthalpy, 94.6 kJ/mol, and on the assumption that the activation enthalpy for product recombination is negligible. of formation, Δ f H o liquid? [all data], Dennenberg and Darensbourg, 1972 Ungváry, F.; Markó, L., . J. Phys. Chem. [all data], Al-Takhin, Connor, et al., 1984, 2 K and T = 303. This page allows searching J. Chem. . errors or omissions in the Database. [all data], Stull, 1947 Specific heat of Carbon Monoxide Gas - CO - at temperatures ranging 175 - 6000 K: Soc., 1993, 115, 3174. Using the information given in the reactions below, calculate the heat of formation for 1 mole of carbon monoxide. Chem.     Cp = heat capacity (J/mol*K) Google use cookies for serving our ads and handling visitor statistics. Chem., 1981, 85, 1620. Am. Venkataraman, B.K. Proc. [all data], Hieber and Romberg, 1935 Energetics and Structure of Na+ Cluster Ions, ; Skinner, H.A. Your institution may already be a subscriber. High-Pressure Mass Spectrometric Study of Reactions of Rare Gases with N2 and CO, Chem. . Chem., 1975, 97, 221. Chemical, physical and thermal properties of Carbon Monoxide - CO :(values at 25oC (77oF, 298 K) and atmospheric pressure). Ray, U.; Brandow, S.L. Koelliker, R.; Bor, G., Atti Accad. Chem. . Phys., 1971, 54, 4, 1487, https://doi.org/10.1063/1.1675043 Please read Google Privacy & Terms for more information about how you can control adserving and the information collected. Cetini, G.; Gambino, O., ; Brown, E.G., Follow the links above to find out more about the data R. Acad. J. (solution) +  (solution) = C14H21MnO2 (solution) +  (solution), By formula: C8H5MnO3 (solution) + C7H16 (solution) = C14H21MnO2 (solution) + CO (solution), (solution) +  (solution) = C12H16CrO5 (solution) +  (solution), By formula: C6CrO6 (solution) + C7H16 (solution) = C12H16CrO5 (solution) + CO (solution), (solution) = C5CrO5 (solution) +  (solution), By formula: C6CrO6 (solution) = C5CrO5 (solution) + CO (solution), (solution) = C5MoO5 (solution) +  (solution), By formula: C6MoO6 (solution) = C5MoO5 (solution) + CO (solution), (solution) = C5O5W (solution) +  (solution), By formula: C6O6W (solution) = C5O5W (solution) + CO (solution), C11H2O11Os (solution) +  (solution) =  (g) +  (solution), By formula: C11H2O11Os (solution) + CO (solution) = H2 (g) + C12O12Os3 (solution), By formula: C5FeO5 (g) = C4FeO4 (g) + CO (g), By formula: C6MoO6 (g) = C5MoO5 (g) + CO (g), By formula: C6O6W (g) = C5O5W (g) + CO (g), By formula: C6CrO6 (g) = C5CrO5 (g) + CO (g), C10H5CrNO5 (solution) +  (solution) =  (solution) +  (solution), By formula: C10H5CrNO5 (solution) + CO (solution) = C6CrO6 (solution) + C4H4N2 (solution), By formula: C6O6W (cr) = 6CO (g) + W (cr), (solution) + 3 (solution) = 3C5O5Ru (solution), By formula: C12O12Ru3 (solution) + 3CO (solution) = 3C5O5Ru (solution), (solution) = C7Co2O7 (solution) +  (solution), By formula: C8Co2O8 (solution) = C7Co2O7 (solution) + CO (solution), By formula: C6O6W (cr) + C4H4N2 (l) = C10H5NO5W (cr) + CO (g), (solution) +  (solution) = C12H16MoO5 (solution) +  (solution), By formula: C6MoO6 (solution) + C7H16 (solution) = C12H16MoO5 (solution) + CO (solution), By formula: C2FeO2 (g) = CO (g) + CFeO (g), By formula: C4NiO4 (g) = 4CO (g) + Ni (cr), By formula: C3FeO3 (g) = CO (g) + C2FeO2 (g), By formula: C4FeO4 (g) = C3FeO3 (g) + CO (g), (solution) = C3NiO3 (solution) +  (solution), By formula: C4NiO4 (solution) = C3NiO3 (solution) + CO (solution), (CAS Reg.